Sulfur isotope fractionation and sequential extraction to assess metal contamination on lake and river sediments
نویسندگان
چکیده
منابع مشابه
Sulfur biogeochemistry and isotopic fractionation in shallow groundwater and sediments of Owens Dry Lake, California
Groundwater and sediment samples (~1 m depth) at sites representative of different groundwater pathways were collected to determine the aqueous speciation of sulfur and the fractionation of sulfur isotopes in aqueous and solid phases. In addition, selected sediment samples at 5 depths (from oxic to anoxic layers) were collected to investigate the processes controlling sulfur biogeochemistry in ...
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Sequential extraction and radiotracer analyses were used to evaluate the geochemical partitioning of metals (Pb, Cd, Cr, and Cu) in the sediments of Lake Victoria to partition the contribution of catchment areas. Highest total concentration and enrichments of Pb, Cd and Cr occurred near river inlets from polluted urban areas discharging municipal effluents into the rivers. Partitioning coeffici...
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The role of sediment-bound organic phosphorus (Po) on lake eutrophication was studied using sequential extraction and enzymatic hydrolysis by collecting sediments from Dianchi Lake, China. Bioavailable Po species including labile monoester P, diester P, and phytate-like P were identified in the sequential extractions by H2O, NaHCO3, and NaOH. For the H2O-Po, 36.7% (average) was labile monoester...
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The discovery by Farquhar et al. (1) of mass-independent isotope fractionation of S and S in rocks formed more than ;2 billion years ago (Ga), but not in younger rocks, has boosted the theory postulating a dramatic change from an anoxic to an oxygen-rich atmosphere about 2 Ga. That is because the only known natural process that may cause mass-independent fractionation of both S and S involves a...
متن کاملMass-independent sulfur isotope fractionation during photochemistry of sulfur dioxide
Mass-independent sulfur isotope signatures are observed in Archean and early Paleoproterozoic sedimentary sulfate and sulfide minerals, and provide the most robust constraints on early atmospheric oxygen levels. Smaller mass-independent sulfur isotope anomalies are observed in ice cores and interpreted as a tracer of stratospheric volcanic loading. Photochemistry of sulfur dioxide (SO 2) has be...
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ژورنال
عنوان ژورنال: Journal of Soils and Sediments
سال: 2016
ISSN: 1439-0108,1614-7480
DOI: 10.1007/s11368-016-1410-9